EDIT: With the 1.1.1 release, this feature can now be set in the preferences window.
When BravoTunes is opened, it can automatically launch iTunes. There is a checkbox labeled ‘Always Use This Answer’. It occurred to me, however, that if you click this option and then change your mind, there is no way via the preferences window to change this behavior (oops!).

So until I correct this in the next update, here’s how you can change this option directly, via the OS X Terminal, if you need to.
If BravoTunes is launching iTunes every time it starts up, and you want to stop that (or vice versa, you clicked “Don’t Open” and now you want it to launch iTunes), do this:
Step 1. Open up Terminal.app (you’ll find it in your /Applications/Utilities/ folder)
Step 2. Type the command below to enable iTunes auto-launching:
defaults write com.bravobug.BravoTunes launchiTunes -bool YES
Or, if you want to disable it so that iTunes doesn’t automatically launch:
defaults write com.bravobug.BravoTunes launchiTunes -bool NO
That’s all there is to it. I should also point out that if you have iTunes auto-launch enabled, you will typically want to quit BravoTunes before you quit iTunes. Under certain conditions if you quit iTunes first, BravoTunes may try to open iTunes back up automatically (which can be annoying – I’m working on fixing this behavior).
Thanks for visiting.